Molecular Theory of Capillarity
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A discussion of statistical mechanics leads to the application of results in mean-field approximation to some tractable but artificial model systems. More realistic models are portrayed both by computer simulation and by approximation to some portrayed both by computer simulation and by approximations of the precise statistical equations. Emphasis throughout the text is consistently placed on the liquid-gas surface, with a focus on liquid-liquid surfaces in the final two chapters.
Students, teachers, and professionals will find in this volume a comprehensive account of the field: theorists will encounter novel problems to which to apply the basic principles of thermodynamics, and industrial scientists will deem it an invaluable guide to understanding and predicting the properties of the interfacial region.
Its extensive cross-referencing effectively assembles many diverse topics and theoretical approaches, making this book indispensable to all those engaged in research into interfaces in fluid-phase equilibria. Country of Publication: US Dimensions cm : Help Centre. Track My Order. My Wishlist Sign In Join.
van der Waals, Johannes Diderik | Infoplease
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Molecular Theory of Capillarity
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No additional import charges at delivery! This item will be shipped through the Global Shipping Program and includes international tracking. Water is a liquid that wets glass capillary tubes; mercury is one that does not. When wetting does not occur, capillarity does not occur. Capillarity is the result of surface, or interfacial, forces. The rise of water in a thin tube inserted in water is caused by forces of attraction between the molecules of water and the glass walls and among the molecules of water themselves. These attractive forces just balance the force of gravity of the column of water that has risen to a characteristic height.
The narrower the bore of the capillary tube, the higher the water rises. Mercury, conversely, is depressed to a greater degree, the narrower the bore. Article Media. Info Print Cite.